全文获取类型
收费全文 | 344篇 |
免费 | 12篇 |
国内免费 | 31篇 |
专业分类
测绘学 | 212篇 |
大气科学 | 1篇 |
地球物理 | 46篇 |
地质学 | 63篇 |
海洋学 | 44篇 |
综合类 | 11篇 |
自然地理 | 10篇 |
出版年
2024年 | 1篇 |
2023年 | 5篇 |
2022年 | 8篇 |
2021年 | 14篇 |
2020年 | 12篇 |
2019年 | 7篇 |
2018年 | 6篇 |
2017年 | 35篇 |
2016年 | 17篇 |
2015年 | 21篇 |
2014年 | 29篇 |
2013年 | 15篇 |
2012年 | 29篇 |
2011年 | 20篇 |
2010年 | 13篇 |
2009年 | 26篇 |
2008年 | 18篇 |
2007年 | 25篇 |
2006年 | 26篇 |
2005年 | 14篇 |
2004年 | 13篇 |
2003年 | 10篇 |
2002年 | 9篇 |
2000年 | 9篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1995年 | 1篇 |
1992年 | 1篇 |
排序方式: 共有387条查询结果,搜索用时 15 毫秒
1.
近海环境地球化学调查研究历史与现状 总被引:1,自引:0,他引:1
近海环境地球化学的研究是一支新兴的发展中的边缘性分支学科,由于环境问题的日益突出,该学科发展较为迅速。通过回顾我国近海环境地球化学调查的历史和综述当今国外该学科的研究现状,概括了该学科的主要进展,并指出存在的问题和今后的发展方向。 相似文献
2.
3.
Elizabeth B. Kujawinski Rossana Del Vecchio Neil V. Blough Geoffrey C. Klein Alan G. Marshall 《Marine Chemistry》2004,92(1-4):23
Molecular-level characterization of natural organic matter (NOM) has been elusive due to the inherent complexity of natural organic mixtures and to the fact that individual components are often polar and macromolecular. Electrospray ionization (ESI) is a “soft” ionization technique that ionizes polar compounds from aqueous solution prior to injection into a mass spectrometer. The highest resolution and mass accuracy of compounds within NOM have been achieved when ESI is combined with an ultrahigh-resolution mass spectrometer such as the Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS). With this technique, individual molecules within a variety of natural organic mixtures can be detected and their elemental composition can be determined. At low mass-to-charge (m/z) ratio, the resolution is high enough to assign exact molecular formulas allowing specific components of these mixtures to be identified. In addition to molecular identification, we can now use ESI FT-ICR MS to examine molecular-level changes in different organic mixtures as a function of relevant geo-processes, such as microbial alterations and photochemistry. Here we present the results from the application of ESI FT-ICR MS to two geochemical questions: (1) the effect of photoirradiation on the molecular composition of fulvic acids and (2) the role of protozoan grazers in the modification of DOM in aquatic systems. 相似文献
4.
海水中低含量铵氮的高灵敏度荧光法测定 总被引:3,自引:0,他引:3
提出了一种改进的、可测定海水中低含量铵氮的高灵敏度荧光分析方法。其原理是在硼酸缓冲溶液的作用下,海水中的铵氮与邻苯二甲醛(OPA)发生衍生化反应,通过测定生成的荧光产物来确定水体中铵氮的浓度。方法的检测限极低(0.002 5μmol/L),重现性好,且水样用量少(10 mL),适用于海水中溶解有机物的光铵化研究及其他低铵含量水样的测定。 相似文献
5.
Mucous macroaggregates, recently observed in the northern Adriatic in summer of 1997 and late spring of 2000, are primarily the product of phytoplankton (diatom) exudates during favourable environmental conditions in late spring, and can be viewed as macrogels. The FT-IR and 1H-NMR spectra of macroaggregate samples from the northern Adriatic, collected in different formation stages in July 1997, August 1997, September 1997 and June 2000, as well as of cultured diatom Skeletonema costatum, showed that they are similar and composed of aliphatic components and polysaccharides bonded through carboxylic and amide groups, and organosilicon compounds. The stability of macrogels of macroaggregates is, according to FT-IR and X-ray analyses, most probably enhanced by interactions with entrapped particles of calcite, quartz and clay minerals. These organic-mineral associations seem to be important for mucous phenomena. According to 1H-NMR spectra, the temporal differences in macroaggregate composition show a relative increasing percentage of organosilicon compounds and aliphatic components bonded to carbohydrates through ester and amide groups, and an increasing ratio between aliphatic structures and carbohydrates. This indicates that aliphatic chains bonded to Si and carbohydrates may contribute to the persistence and stability of macroaggregates in the summer stratified waters in the northern Adriatic, while the temporal decrease of carbohydrate content is most probably due to microbial and photochemical degradation of algal reserve polysaccharides. 相似文献
6.
7.
基于GDI+的GML可视化模型设计 总被引:1,自引:0,他引:1
本文介绍了基于GML地理数据的可视化模型设计方法。利用文档对象模型(DOM)对GML进行解析,以及通过对GD I+自身特性的分析,展示了在.NET环境下采用GD I+类库进行可视化模型设计的优良特性,为实现GML数据可视化提供了一个切实可行的方案。 相似文献
8.
SPOT-5影像的高分辨率和高信息量的性质,使其得到了广泛的应用,特别是在全国第二次土地利用调查中得到了更加深入的应用。而数字正射影像的制作是SPOT-5遥感影像应用的关键所在。本文在介绍DOM制作的基础上,依据当前获取GCP主要的三种途径采用ERDAS遥感图像处理软件进行了实验,并对最终的结果精度进行分析,总结了DOM制作过程的相关问题。 相似文献
9.
10.
Domy C. Adriano Hyo T. Chon Sally L. Brown Rosanna Ginocchio 《中国地球化学学报》2006,25(B08):45-46
Metals, including heavy metals and metalloids, are a common group of environmental contaminants. Their sources in the environment are geogenic or anthropogenic. The growing trend in global industrialization ensures that more metals could be dispersed even in pristine ecosystems. To fuel industrialization, more metal ore mines have to be discovered and explored. These explorations often result in landscape disturbance, soil degradation and environmental contamination by unwanted mining constituents. Mine tailings brought up to the ground surface often serve as the main source of contaminants when these pyrite-rich materials oxidize. The oxidation of mine tailings results in proton generation, coupled with the dissolution of metals and other cations Unwanted anionic constituents are also produced. The so-called "acid mine drainage" may affect the productivity of farmlands and stability of receiving streams and other bodies of water-acidifying the waters and enriching the ecosystem with metals, i.e., high total dissolved solids. The acidified overburden materials become inhospitable to plant and microbial life as they are typically low in organic matter content and infertile. This exposes the landscape to runoff and erosion. 相似文献